Product ID:P9030, POLYVINYLPYRROLIDONE AV MOL (SUPDAT)
MSDS Date:01/01/1999
FSC:6550
NIIN:00N093172
Status Code:A
MSDS Number: CJXGX

Emergency Phone: 314-771-5765

Info Phone: 314-771-5765

Cage: 21076

Telephone: 314-771-5765

Cage: 21076

POLY(VINYLPYRROLIDONE)

CAS: 9003-39-8

RTECS: TR8160000

LD50 LC50 Mixture:LD50: (ORAL,RAT) 100 GM/KG
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO
Health Hazards Acute and Chronic:ACUTE EFFECTS: MAY BE HARMFUL BY
INHALATION, INGESTION, OR SKIN ABSORPTION. MAY CAUSE EYE
IRRITATION. MAY CAUSE SKIN IRRITATION. MATERIAL MAY BE IRRITATING
TO MUCOUS MEMBRANES AND UPPER RESPIRATORY TR ACT. TO THE BEST OF
OUR KNOWLEDGE, THE CHEMICAL, PHYSICAL, AND TOXICOLOGICAL PROPERTIES
HAVE NOT BEEN THOROUGHLY INVESTIGATED. ADDNL INFO: UNEXCRETED
PARTICLES MAY BE PHAGOCYTIZED BY CELLS OF THE RETI CULOENDOTHELIAL
SYSTEM & DEPOSITED IN STORAGE SITES IN THE LIVER, SPLEEN, LUNG,
BONE MARROW RESULTING IN THE STORAGE DISEASE THESAUROSIS. SEVERITY
AND SYMPTOMS DEPEND ON STORAGE SITE AND NATURE OF (EF TS OF
OVEREXP)
Effects of Overexposure:HLTH HAZS: THE PARTICLE. PATHOLOGICAL CHANGES
ARE NOT NECESSARILY ATTRIBUTED TO THE THESAUROSIS, BUT IN SOME
CASES AN INFLAMMATION OR GRANULOMATOMA HAVE OCCURRED. THIS MATERIAL
IS CLASSIFIED BY IARC ( INTERNATIONAL AGENCY FOR RESEARCH ON
CANCER) AS GROUP 3 WITH LIMITED ANIMAL EVIDENCE FOR CARCINOGENICITY
AND NO ADEQUATE DATA FOR HUMAN CARCINOGENICITY CLASSIFICATION.

First Aid:IN CASE OF CONTACT, IMMEDIATELY FLUSH EYES WITH COPIOUS
AMOUNTS OF WATER FOR AT LEAST 15 MINUTES. FLUSH SKIN WITH WATER. IF
INHALED, REMOVE TO FRESH AIR. IF SWALLOWED, WASH OUT MOUTH WITH
WATER PROVID ED PERSON IS CONSCIOUS.

Extinguishing Media:WATER SPRAY. CARBON DIOXIDE, DRY CHEMICAL POWDER OR
APPROPRIATE FOAM.
Fire Fighting Procedures:USE NIOSH APPROVED SCBA AND FULL PROTECTIVE
EQUIPMENT .
Unusual Fire/Explosion Hazard:EMITS TOXIC FUMES UNDER FIRE CONDTIONS.

Spill Release Procedures:CHEMICAL SAFETY GOGGLES. USE PROTECTIVE
CLOTHING, GLOVES AND MASK. SWEEP UP, PLACE IN A BAG AND HOLD FOR
WASTE DISPOSAL. AVOID RAISING DUST. VENTILATE AREA AND WASH SPILL
SITE AFTER MATERIAL PICKUP IS COMPLETE.

Handling and Storage Precautions:DO NOT BREATHE DUST. DO NOT GET IN
EYES, ON SKIN, ON CLOTHING. AVOID PROLONGED OR REPEATED EXPOSURE.
KEEP TIGHTLY CLOSED. STORE IN A COOL DRY PLACE.

Respiratory Protection:WEAR APPROPRIATE NIOSH APPROVED RESPIRATOR.
Ventilation:USE ONLY IN A CHEMICAL FUME HOOD.
Protective Gloves:CHEMICAL-RESISTANT GLOVES.
Eye Protection:ANSI APPROVED CHEMICAL WORKERS GOGGLES .
Other Protective Equipment:EYE WASH & DELUGE SHOWER MEETING ANSI DESIGN
CRITERIA . OTHER PROTECTIVE CLOTHING.
Work Hygienic Practices:WASH THOROUGHLY AFTER HANDLING.
Supplemental Safety and Health
MFR TRADE NAME/PART NO: WT 40,000 EMBRYO TESTED.

Appearance and Odor:SOLID.

Stability Indicator/Materials to Avoid:YES
STRONG OXIDIZING AGENTS.
Hazardous Decomposition Products:THERMAL DECOMPOSITION MAY PRODUCE
CARBON MONOXIDE, CARBON DIOXIDE, AND NITROGEN OXIDES.

Waste Disposal Methods:DISSOLVE OR MIX THE MATERIAL WITH A COMBUSTIBLE
SOLVENT AND BURN IN A CHEMICAL INCINERATOR EQUIPPED WITH AN
AFTERBURNER AND SCRUBBER. OBSERVE ALL FEDERAL, STATE AND LOCAL
ENVIRONMENTAL REGULATIONS.

Toxicological Information:SEE HEALTH HAZARDS. RTECS #: TR8370000.
POLY(1-VINYL-2-PYRROLIDINONE) HOMOPOLYMER. TOX DATA: ORL-RAT
LD50:100 GM/KG FAONAU 53A,486,1974. ORL-MUS LD50:>40 GM/KG FAONAU
40,164,1967. IPR-MUS LD50:12 GM/K G FAONAU 53A,486,1974. UNR-MUS
LD50:16 GM/KG. KHFZAN 19,212,1985. ORL-RBT LD50:1040 MG/KG VETNAL
61(12),68,1985. ORL-GPG LD50:100 GM/KG FAONAU 53A,486,1974. ONLY
SELECTED REGISTRY OF TOXIC EFFECTS OF CHEMICAL SUBSTANCES (RTECS)
DATA IS PRESENTED HERE. SEE ACTUAL ENTRY IN RTECS FOR COMPLETE
INFORMATION.

Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.

Ecological:DATA NOT YET AVAILABLE.

Transport Information:CONTACT SIGMA CHEMICAL COMPANY FOR TRANSPORTATION
INFORMATION.

Federal Regulatory Information:EUROPEN INFORMATION. CAUTION: SUBSTANCE
NOT YET FULLY TESTED. REVIEWS, STANDARDS, AND REGULATIONS. OEL=MAK.
IARC CANCER REVIEW:ANIMAL LIMITED EVIDENCE IMEMDT 19,461,1979. IARC
CANCER REVIEW:HUMAN NO A DEQUATE DATA IMEMDT 19,461,1979. IARC
CANCER REVIEW:GROUP 3 IMSUDL 7,56,1987. NOHS 1974: HZD 81235; NIS
50; TNF 7856; NOS 63; TNE 102100. NOES 1983: HZD X7211; NIS 46; TNF
7688; NOS 63; TNE 161259; TF E 84819. EPA TSCA SECTION 8(B)
CHEMICAL INVENTORY. EPA TSCA SECTION 8(D) UNPUBLISHED HEALTH/SAFETY
S TUDIES. EPA TSCA TEST SUBMISSION (TSCATS) DATA BASE, JUNE 1998.